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Beilstein J. Org. Chem. 2007, 3, No. 16, doi:10.1186/1860-5397-3-16
Graphical Abstract
Scheme 1: The silylcupration of allenes.
Scheme 2: Silylcupration of 1,2-propadiene and reaction with oxo compounds.
Scheme 3: Silicon assisted cyclization of oxoallylsilanes.
Scheme 4: Silylcupration of terminal alkynes bearing electron-withdrawing functions.
Scheme 5: The acid-catalyzed cyclization of epoxyallylsilanes.
Scheme 6: Intramolecular cyclization of TMS-epoxyallylsilanes.
Scheme 7: Spiro-cyclopropanation from oxoallylsilanes.
Scheme 8: Cyclobutane formation from hydroxy-functionalized allysilanes.
Scheme 9: Cyclobutene formation from vinyltin cuprates and epoxides.
Scheme 10: Silylcupration of 1,2-propadiene and reaction with α,β-unsaturated nitriles.
Scheme 11: Cycloheptane formation from silylcupration of α,β-unsaturated imines.
Scheme 12: Seven membered ring formation from functionalized allylsilanes.